This course is divided in 3 major sections:
Section I:
The fundamental concepts and theory related to unit testing in general, regardless of programming language;
Section II:
The fundamental techniques and features of JUnit 4 (a pre-requisite for part II of the course);
Section III:
The architecture and extension model introduced in JUnit 5;
The advanced techniques and features introduced in JUnit 5.
If you are a totally new to unit testing in general and unit testing in Java in particular then I highly recommend that you take the three sections in the order presented above.
If you're familiar with JUnit 4 then you may skip Section II. I'd still recommend that you take Section I though since it introduces fundamental concepts that you may not be familiar with pertaining with unit testing in general even if you've some experience in JUnit 4.